Issue 8, 2001
From the journal:

Chemical Communications

Unprecedented formation of

Pavel Lhoták,*a   Miroslav Dudicč,a   Ivan Stibor,a   Hana Petříčková,b   Jan Sýkorab  and  Jana Hodačovác  

* Corresponding authors

a Department of Organic Chemistry, Institute of Chemical Technology, Technická 5, Prague 6, Czech Republic.
E-mail: lhotakp@vscht.cz

b Department of Solid State Chemistry, Institute of Chemical Technology, Technická 5, Prague 6, Czech Republic

c Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo 2, Prague 6, Czech Republic

Abstract

Distal bis(carboxymethyloxy) derivatives of thiacalix[4]arene were found to undergo an unprecedented intramolecular cyclisation to yield lactone compounds 5a or 5b, the structure of lactones possessing nine-membered ring was proved by X-ray crystallography; inherent chirality of new compounds was demonstrated using separation on a chiral HPLC column.

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DOI
https://doi.org/10.1039/B100906K
Article type
Communication
Submitted
25 Jan 2001
Accepted
08 Mar 2001
First published
30 Mar 2001

Chem. Commun., 2001, 731-732

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Unprecedented formation of lactone derivatives in thiacalix[4]arene series

P. Lhoták, M. Dudicč, I. Stibor, H. Petříčková, J. Sýkora and J. Hodačová, Chem. Commun., 2001, 731 DOI: 10.1039/B100906K

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