Issue 18, 2001
From the journal:

Chemical Communications

New high-nuclearity Ni–Pt carbonyl clusters: synthesis and X-ray structure of the ordered [Ni24Pt14(CO)44]4− and the substitutionally Ni/Pt disordered [Ni10(Ni6−xPtx )Pt8(CO)30]4− (x = 1.92) tetraanions

Cristina Femoni,a   M. Carmela Iapalucci,a   Giuliano Longoni*a  and  Per H. Svenssona  

* Corresponding authors

a Dipartimento di Chimica Fisica ed Inorganica, Università di Bologna, viale Risorgimento 4, Bologna, Italy.
E-mail: longoni@ms.fci.unibo.it

Abstract

The reaction of [NnBu4]2[Ni6(CO) 12] in THF solution with 1.5–2 equivalents of K2PtCl4 leads to formation of the [Ni24Pt14(CO)44]4− and [Ni10(Ni6−xPtx )Pt8(CO)30]4− (x≈2) tetraanions, the latter presents a localised substitutional Ni/Pt disorder and an unprecedented close-packed metal structure.

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Article information

DOI
https://doi.org/10.1039/B103610F
Article type
Communication
Submitted
23 Apr 2001
Accepted
30 Jul 2001
First published
03 Sep 2001

Chem. Commun., 2001, 1776-1777

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New high-nuclearity Ni–Pt carbonyl clusters: synthesis and X-ray structure of the ordered [Ni24Pt14(CO)44]4− and the substitutionally Ni/Pt disordered [Ni10(Ni6−xPtx )Pt8(CO)30]4− (x = 1.92) tetraanions

C. Femoni, M. Carmela Iapalucci, G. Longoni and P. H. Svensson, Chem. Commun., 2001, 1776 DOI: 10.1039/B103610F

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