Coordination of pertechnetate [TcO4]− to actinides

Mark J. Sarsfield; Andrew D. Sutton; Iain May; Gordon H. John; Clint Sharrad; Madeleine Helliwell

doi:10.1039/B404424J

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Coordination of pertechnetate [TcO₄]⁻ to actinides†

Mark J. Sarsfield,‡*^a Andrew D. Sutton,^a Iain May,^a Gordon H. John,^a Clint Sharrad^a and Madeleine Helliwell^b

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* Corresponding authors

^a Centre for Radiochemistry Research, Department of Chemistry, The University of Manchester, Manchester, UK
E-mail: mark.j.sarsfield@man.ac.uk
Fax: +44 (0)161 275 4616
Tel: +44 (0)161 275 1405

^b Department of Chemistry, The University of Manchester, Manchester, UK

Abstract

The ability of [TcO₄]⁻ to coordinate directly to tetra- and hexa-valent actinides in the presence of organic P [double bond, length as m-dash] O ligands is confirmed in the crystallographically characterised complexes [UO₂(TcO₄)₂(Ph₃PO)₃] (1) and [Th(TcO₄)₄(ⁿBu₃PO)₄] (2).

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Article information

DOI: https://doi.org/10.1039/B404424J
Article type: Communication
Submitted: 25 Mar 2004
Accepted: 01 Jul 2004
First published: 06 Sep 2004

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Chem. Commun., 2004, 2320-2321

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Coordination of pertechnetate [TcO₄]⁻ to actinides

M. J. Sarsfield, A. D. Sutton, I. May, G. H. John, C. Sharrad and M. Helliwell, Chem. Commun., 2004, 2320 DOI: 10.1039/B404424J

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