Issue 2, 2005

Sequential homobimetallic catalysis: an unprecedented tandem Pd(0)-catalysed deprotection – Pd(ii)-catalysed heterocyclisation reaction leading to benzofurans

Abstract

We report here the first example of “sequential homobimetallic catalysis”: a transition metal catalyst with the metal in a certain oxidation state catalyses the deprotection of a functional group, which in situ undergoes a subsequent transformation catalysed by another complex of the same metal but in a different oxidation state.

Graphical abstract: Sequential homobimetallic catalysis: an unprecedented tandem Pd(0)-catalysed deprotection – Pd(ii)-catalysed heterocyclisation reaction leading to benzofurans

Article information

Article type
Communication
Submitted
31 Aug 2004
Accepted
04 Oct 2004
First published
12 Nov 2004

Chem. Commun., 2005, 271-273

Sequential homobimetallic catalysis: an unprecedented tandem Pd(0)-catalysed deprotection – Pd(II)-catalysed heterocyclisation reaction leading to benzofurans

B. Gabriele, R. Mancuso, G. Salerno and L. Veltri, Chem. Commun., 2005, 271 DOI: 10.1039/B413240H

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