Issue 2, 2005

Molecular tectonics: design of coordinating tectons based on diazamacrocycles bearing pyridine units and formation of 1D copper coordination networks

Abstract

Four new bis monodentate tectons 14 based on the diazadioxa (5)- and diazatetraoxa (6)-macrocyclic backbones bearing two pyridine units as coordinating sites have been designed and prepared. In the presence of copper diacetate, their ability to form coordination networks was demonstrated by structural studies based on X-ray diffraction methods. Both tectons 1 and 2 behave as bis monodentate units and their bridging by copper diacetate dimer behaving as a linear metallatecton leads to the formation of analogous 1D coordination networks.

Graphical abstract: Molecular tectonics: design of coordinating tectons based on diazamacrocycles bearing pyridine units and formation of 1D copper coordination networks

Supplementary files

Article information

Article type
Paper
Submitted
19 Oct 2004
Accepted
23 Nov 2004
First published
06 Jan 2005

New J. Chem., 2005,29, 343-346

Molecular tectonics: design of coordinating tectons based on diazamacrocycles bearing pyridine units and formation of 1D copper coordination networks

E. Graf, M. Wais Hosseini, J. Planeix and N. Kyritsakas, New J. Chem., 2005, 29, 343 DOI: 10.1039/B416145A

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