Issue 19, 2005
From the journal:

Chemical Communications

Synthesis and crystal structure of a push–pull quinoidal porphyrin: a nanoporous framework assembled from cyclic trimer aggregates†

Martin J. Smith,a   William Clegg,b   Kiet A. Nguyen,c   Joy E. Rogers,c   Ruth Pachter,c   Paul A. Fleitzc  and  Harry L. Anderson*a  

* Corresponding authors

a Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, UK
E-mail: harry.anderson@chem.ox.ac.uk
Fax: +44(0)1865 285002
Tel: +44(0)1865 275704

b Department of Chemistry, University of Newcastle, Newcastle upon Tyne, UK NE1 7RU, and CCLRC Daresbury Laboratory, Warrington, UK

c Air Force Research Laboratory, AFRL/MLPJ, 3005 Hobson Way, Wright-Patterson Air Force Base, Dayton, Ohio, USA

Abstract

A quinoidal porphyrin has been synthesised with such a curved π-system that π–π stacking leads to the formation of cyclic trimer aggregates in the crystal, which pack to generate cylindrical channels with an internal diameter of 1.0 nm.

Graphical abstract: Synthesis and crystal structure of a push–pull quinoidal porphyrin: a nanoporous framework assembled from cyclic trimer aggregates

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Article information

DOI
https://doi.org/10.1039/B502776D
Article type
Communication
Submitted
24 Feb 2005
Accepted
22 Mar 2005
First published
13 Apr 2005

Chem. Commun., 2005, 2433-2435

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Synthesis and crystal structure of a push–pull quinoidal porphyrin: a nanoporous framework assembled from cyclic trimer aggregates

M. J. Smith, W. Clegg, K. A. Nguyen, J. E. Rogers, R. Pachter, P. A. Fleitz and H. L. Anderson, Chem. Commun., 2005, 2433 DOI: 10.1039/B502776D

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