Issue 26, 2005
From the journal:

Chemical Communications

A readily prepared neutral heterobimetallic titanium(iv)–rhodium(i) catalyst for intramolecular hydroacylation†

John P. Morgan,*a   Kousik Kundu*a  and  Michael P. Doylea  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, USA
E-mail: jpmorgan@umd.edu, kousik@glue.umd.edu.
Fax: 301.314.9121
Tel: 301-405-1327

Abstract

The combination of HOCMe2CH2PPh2, Ti(OiPr)4, and [Rh(cod)Cl]2 (3∶1∶1) in either benzene or dichloromethane produces a discrete species (tentatively formulated as complex 14) that is an active catalyst for intramolecular hydroacylation reactions of 3-substituted pentenals.

Graphical abstract: A readily prepared neutral heterobimetallic titanium(iv)–rhodium(i) catalyst for intramolecular hydroacylation

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Article information

DOI
https://doi.org/10.1039/B504195C
Article type
Communication
Submitted
24 Mar 2005
Accepted
03 May 2005
First published
01 Jun 2005

Chem. Commun., 2005, 3307-3309

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A readily prepared neutral heterobimetallic titanium(IV)–rhodium(I) catalyst for intramolecular hydroacylation

J. P. Morgan, K. Kundu and M. P. Doyle, Chem. Commun., 2005, 3307 DOI: 10.1039/B504195C

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