Issue 28, 2005
From the journal:

Chemical Communications

Polyethyl substituted weakly coordinating carborane anions: a sequential dehydrogenative borylation–hydrogenation route†

Eduardo Molinos,a   Gabriele Kociok-Köhna  and  Andrew S. Weller*a  

* Corresponding authors

a Department of Chemistry, University of Bath, Bath, UK
E-mail: a.s.weller@bath.ac.uk
Fax: +44(0)1225386231
Tel: +44(0)1225383394

Abstract

Polyethylated carborane monoanions based on [closo-CB11H12]− with up to five B-ethyl groups can be prepared by a sequential Rh-catalysed dehydrogenative borylation then hydrogenation.

Graphical abstract: Polyethyl substituted weakly coordinating carborane anions: a sequential dehydrogenative borylation–hydrogenation route

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Article information

DOI
https://doi.org/10.1039/B504630K
Article type
Communication
Submitted
05 Apr 2005
Accepted
16 May 2005
First published
09 Jun 2005

Chem. Commun., 2005, 3609-3611

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Polyethyl substituted weakly coordinating carborane anions: a sequential dehydrogenative borylation–hydrogenation route

E. Molinos, G. Kociok-Köhn and A. S. Weller, Chem. Commun., 2005, 3609 DOI: 10.1039/B504630K

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