Issue 42, 2005
From the journal:

Chemical Communications

Regiochemical control of the catalytic asymmetric hydroboration of 1,2-diarylalkenes

Antonia Black,a   John M. Brown*a  and  Christophe Pichon†a  

* Corresponding authors

a Chemical Research Laboratory, Mansfield Rd., Oxford, UK
E-mail: john.brown@chem.ox.ac.uk
Fax: 44 1865 285002
Tel: 44 1865 275642

Abstract

The hydroboration of stilbenes and related disubstituted alkenes catalysed by QUINAP complexes may proceed with high enantio- and regioselectivity; rhodium and iridium catalysts give the same product regioisomer but opposite enantiomers.

Graphical abstract: Regiochemical control of the catalytic asymmetric hydroboration of 1,2-diarylalkenes

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Article information

DOI
https://doi.org/10.1039/B508292G
Article type
Communication
Submitted
13 Jun 2005
Accepted
16 Sep 2005
First published
05 Oct 2005

Chem. Commun., 2005, 5284-5286

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Regiochemical control of the catalytic asymmetric hydroboration of 1,2-diarylalkenes

A. Black, J. M. Brown and C. Pichon, Chem. Commun., 2005, 5284 DOI: 10.1039/B508292G

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