Stabilisation of a paramagnetic BH4−-bridged dinickel(II) complex by a macrodinucleating hexaaza-dithiophenolate ligand

Yves Journaux; Vasile Lozan; Julia Klingele; Berthold Kersting

doi:10.1039/B512744K

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Stabilisation of a paramagnetic BH₄⁻-bridged dinickel(ii) complex by a macrodinucleating hexaaza-dithiophenolate ligand†

Yves Journaux,*^a Vasile Lozan,^b Julia Klingele ‡^b and Berthold Kersting*^b

Author affiliations

* Corresponding authors

^a Laboratoire de Chimie Inorganique et Matériaux Moléculaires Bat F UMR CNRS 7071, case courrier 42, Université Pierre et Marie Curie, 4 place Jussieu, Paris cedex 05, France
E-mail: jour@ccr.jussieu.fr
Tel: +33 14427 5562

^b Institut für Anorganische Chemie, Johannisallee 29, Universität Leipzig, D-04013 Leipzig, Germany
E-mail: b.kersting@uni-leipzig.de
Fax: +49-341-9736199
Tel: +49-341-9736143

Abstract

The first paramagnetic borohydrido-bridged dinuclear nickel(II) complex, [(L)Ni^II₂(μ_1,3-BH₄)]⁺, stabilised by a sterically demanding hexaaza-dithiophenolate macrocycle, has been obtained by the reaction of [(L)Ni^II₂(μ-ClO₄)]⁺ with NⁿBu₄BH₄.

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Article information

DOI: https://doi.org/10.1039/B512744K
Article type: Communication
Submitted: 09 Sep 2005
Accepted: 10 Nov 2005
First published: 23 Nov 2005

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Chem. Commun., 2006, 83-84

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Stabilisation of a paramagnetic BH₄⁻-bridged dinickel(II) complex by a macrodinucleating hexaaza-dithiophenolate ligand

Y. Journaux, V. Lozan, J. Klingele and B. Kersting, Chem. Commun., 2006, 83 DOI: 10.1039/B512744K

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