Issue 33, 2006

First example of a di-cadmium tris-phthalocyanine triple-decker sandwich complex

Abstract

An unprecedented M(II)2Pc3 (M = Cd) triple-decker sandwich complex has been synthesized and characterised by single crystal X-ray crystallography; cyclic voltammetry shows an unusually large range of redox states and EPR spectroscopy indicates that the material exists in at least two redox states, one having spin ½.

Graphical abstract: First example of a di-cadmium tris-phthalocyanine triple-decker sandwich complex

Supplementary files

Article information

Article type
Communication
Submitted
08 May 2006
Accepted
16 Jun 2006
First published
14 Jul 2006

Chem. Commun., 2006, 3504-3506

First example of a di-cadmium tris-phthalocyanine triple-decker sandwich complex

I. Chambrier, D. L. Hughes, J. C. Swarts, B. Isare and M. J. Cook, Chem. Commun., 2006, 3504 DOI: 10.1039/B606416G

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