Issue 41, 2006
From the journal:

Chemical Communications

In situ investigation of the oxidative addition in homogeneous Pd catalysts by synchronised time resolved UV-Vis/EXAFS†

Gemma Guilera,*a   Mark A. Newton,a   Charlene Polli,a   Sakura Pascarelli,a   Meritxell Guinób  and  King Kuog (Mimi) Hii*b  

* Corresponding authors

a European Synchrotron Radiation Facility (ESRF, ID24), P.O. Box 220, 38043 Grenoble Cedex, France
E-mail: guilera@esrf.fr
Fax: +33 (0)4 7688 2784
Tel: +33 (0)4 3888 1930

b Department of Chemistry, Imperial College London, Exhibition Road, South Kensington, UK
E-mail: mimi.hii@imperial.ac.uk
Fax: +44 (0)20 7594 5804
Tel: +44 (0)20 7594 1142

Abstract

Simultaneous structuro-kinetic information obtained via time resolved stopped-flow/UV-Vis spectroscopy/dispersive EXAFS (EDE) experiments elucidated a two-step process for the addition of iodobenzene to [(Ph3P)2Pd(dba)].

Graphical abstract: In situ investigation of the oxidative addition in homogeneous Pd catalysts by synchronised time resolved UV-Vis/EXAFS

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Article information

DOI
https://doi.org/10.1039/B606772G
Article type
Communication
Submitted
12 May 2006
Accepted
14 Aug 2006
First published
04 Sep 2006

Chem. Commun., 2006, 4306-4308

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In situ investigation of the oxidative addition in homogeneous Pd catalysts by synchronised time resolved UV-Vis/EXAFS

G. Guilera, M. A. Newton, C. Polli, S. Pascarelli, M. Guinó and K. K. (. Hii, Chem. Commun., 2006, 4306 DOI: 10.1039/B606772G

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