Issue 44, 2006
From the journal:

Chemical Communications

Synthesis and characterization of a trigonal bipyramidal supramolecular cage based upon rhodium and platinum metal centers†

Jered C. Garrison,a   Matthew J. Panzner,a   Paul D. Custer,a   D. Venkat Reddy,a   Peter L. Rinaldi,a   Claire A. Tessiera  and  Wiley J. Youngs*a  

* Corresponding authors

a Department of Chemistry, The University of Akron, Akron, OH, USA
E-mail: youngs@uakron.edu
Fax: +1-330-972-7370
Tel: +1-330-972-5462

Abstract

The reaction of 4-ethynyl-pyridine with tert-butyl lithium followed by its addition to (Me3tacn)RhCl3 affords the facial octahedral complex (Me3tacn)Rh(CCPy)3, condensation of which with the square planar complex cis-(DCPE)Pt(NO3)2 results in a self-assembled trigonal bipyramidal cage with Rh(III) and Pt(II) atoms occupying the vertices.

Graphical abstract: Synthesis and characterization of a trigonal bipyramidal supramolecular cage based upon rhodium and platinum metal centers

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B608991G
Article type
Communication
Submitted
23 Jun 2006
Accepted
13 Sep 2006
First published
29 Sep 2006

Chem. Commun., 2006, 4644-4646

Permissions

Request permissions

Synthesis and characterization of a trigonal bipyramidal supramolecular cage based upon rhodium and platinum metal centers

J. C. Garrison, M. J. Panzner, P. D. Custer, D. V. Reddy, P. L. Rinaldi, C. A. Tessier and W. J. Youngs, Chem. Commun., 2006, 4644 DOI: 10.1039/B608991G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements