The former “C60F16” is actually a double-caged adduct: (C60F16)(C60)

Alexey A. Goryunkov; Ilya N. Ioffe; Pavel A. Khavrel; Stanislav M. Avdoshenko; Vitaly Yu. Markov; Z. Mazej; Lev N. Sidorov; Sergey I. Troyanov

doi:10.1039/B615457C

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The former “C₆₀F₁₆” is actually a double-caged adduct: (C₆₀F₁₆)(C₆₀)†

Alexey A. Goryunkov,^a Ilya N. Ioffe,^a Pavel A. Khavrel,^a Stanislav M. Avdoshenko,^a Vitaly Yu. Markov,^a Z. Mazej,^b Lev N. Sidorov^a and Sergey I. Troyanov*^a

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* Corresponding authors

^a Moscow State University, Chemistry Department, Leninskiye gory 1, Building 3, Moscow, Russia
E-mail: stroyano@thermo.chem.msu.ru
Fax: +7(495)9391240
Tel: +7(495)9391240

^b Jožef Stefan Institute, Department of Inorganic Chemistry and Technology, Jamova 39, Ljubljana, Slovenia

Abstract

X-ray diffraction study of the substance originally believed to be C₆₀F₁₆ reveals a double-caged structure, (C₆₀F₁₆)(C₆₀); MALDI mass spectra, ¹⁹F NMR spectral data and reasons for stability are discussed.

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Supplementary files

Crystal structure data TXT (29K)

Article information

DOI: https://doi.org/10.1039/B615457C
Article type: Communication
Submitted: 25 Oct 2006
Accepted: 23 Nov 2006
First published: 06 Dec 2006

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Chem. Commun., 2007, 704-706

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The former “C₆₀F₁₆” is actually a double-caged adduct: (C₆₀F₁₆)(C₆₀)

A. A. Goryunkov, I. N. Ioffe, P. A. Khavrel, S. M. Avdoshenko, V. Yu. Markov, Z. Mazej, L. N. Sidorov and S. I. Troyanov, Chem. Commun., 2007, 704 DOI: 10.1039/B615457C

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