Issue 2, 2007
From the journal:

Organic & Biomolecular Chemistry

Photo-Fries reaction in water made selective with a capsule†

Lakshmi S. Kaanumalle,a   Corinne L. D. Gibb,b   Bruce C. Gibb*b  and  V. Ramamurthy*a  

* Corresponding authors

a Department of Chemistry, University of Miami, Coral Gables, Florida, USA
E-mail: murthy1@miami.edu
Fax: +1 305 284 4571
Tel: +1 305 284 1534

b Department of Chemistry, University of New Orleans, New Orleans, Louisiana, USA
E-mail: bgibb@uno.edu
Tel: +1 504 280 3152

Abstract

The water soluble capsule formed by a deep cavity cavitand with eight carboxylic acid groups controls product distribution during photo-Fries rearrangement of naphthyl esters in water by restricting the mobility of primary singletradical pair.

Graphical abstract: Photo-Fries reaction in water made selective with a capsule

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Article information

DOI
https://doi.org/10.1039/B617022F
Article type
Communication
Submitted
21 Nov 2006
Accepted
22 Nov 2006
First published
29 Nov 2006

Org. Biomol. Chem., 2007,5, 236-238

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Photo-Fries reaction in water made selective with a capsule

L. S. Kaanumalle, C. L. D. Gibb, B. C. Gibb and V. Ramamurthy, Org. Biomol. Chem., 2007, 5, 236 DOI: 10.1039/B617022F

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