Macropolyhedral boron-containing cluster chemistry. Synthesis of the nineteen vertex monocarbaborane [9-(terBuNH2)-(anti)-9-CB18H20] by direct carbon-atom Aufbau

Tomáš Jelínek; Ivana Císařová; Bohumil Štíbr; John D. Kennedy

doi:10.1039/B714631K

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Macropolyhedral boron-containing cluster chemistry. Synthesis of the nineteen vertex monocarbaborane [9-(^terBuNH₂)-(anti)-9-CB₁₈H₂₀] by direct carbon-atom Aufbau†

Tomáš Jelínek,^ab Ivana Císařová,^c Bohumil Štíbr^a and John D. Kennedy^b

Author affiliations

^a The Institute of Inorganic Chemistry of the Academy of Sciences of the Czech Republic, Řež-by-Prague, The Czech Republic

^b The School of Chemistry of the University of Leeds, Leeds, UK
E-mail: J.D.Kennedy@leeds.ac.uk.
Fax: +44 133 343 6401
Tel: +44 133 343 6314

^c The Faculty of Natural Science, Charles University in Prague, Albertov 6, Prague 2, The Czech Republic

Abstract

[9-(^terBuNH₂)-(anti)-9-CB₁₈H₂₀], in 36% yield from anti-B₁₈H₂₂, sodium naphthalene and ^terBuNC, constitutes the first example of a clean cluster carbon-addition Aufbau to form a macropolyhedral carbaborane.

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Supplementary files

Crystal structure data TXT (25K)

Article information

DOI: https://doi.org/10.1039/B714631K
Article type: Communication
Submitted: 21 Sep 2007
Accepted: 24 Sep 2007
First published: 03 Oct 2007

Download Citation

Dalton Trans., 2007, 4766-4768

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Macropolyhedral boron-containing cluster chemistry. Synthesis of the nineteen vertex monocarbaborane [9-(^terBuNH₂)-(anti)-9-CB₁₈H₂₀] by direct carbon-atom Aufbau

T. Jelínek, I. Císařová, B. Štíbr and J. D. Kennedy, Dalton Trans., 2007, 4766 DOI: 10.1039/B714631K

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Dalton Transactions