Issue 27, 2008
From the journal:

Chemical Communications

Isolation of an [SNS]Pd(ii) pincer with a water ladder and its Suzuki coupling activity in water†

Shi-Qiang Baia  and  T. S. Andy Hor*a  

* Corresponding authors

a Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore
E-mail: andyhor@nus.edu.sg
Fax: +65-6873-1324

Abstract

A water-compatible Pd(II) pincer with a hybrid [SNS]-donor set, [L1PdCl]Cl·2H2O [L1 = bis-(2-(i-butylsulfanyl)-ethyl)-amine] has been isolated and crystallographically characterized; its solid lattice at 223 K contains a ladder-like water polymer of tetramers and extensive H-bonding exists among the cation, anion and water cluster, and this water-soluble complex is active in Suzuki–Miyaura coupling of phenylboronic acid and selected aryl bromides in water at 75 °C.

Graphical abstract: Isolation of an [SNS]Pd(ii) pincer with a water ladder and its Suzuki coupling activity in water

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Article information

DOI
https://doi.org/10.1039/B802043D
Article type
Communication
Submitted
05 Feb 2008
Accepted
26 Mar 2008
First published
29 Apr 2008

Chem. Commun., 2008, 3172-3174

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Isolation of an [SNS]Pd(II) pincer with a water ladder and its Suzuki coupling activity in water

S. Bai and T. S. A. Hor, Chem. Commun., 2008, 3172 DOI: 10.1039/B802043D

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