Issue 32, 2008
From the journal:

Chemical Communications

Binuclear organometallic ruthenium complexes of a Schiff base expanded porphyrin†

Luciano Cuesta,a   Elisa Tomat,a   Vincent M. Lyncha  and  Jonathan L. Sessler*a  

* Corresponding authors

a Department of Chemistry and Biochemistry and Institute for Cellular and Molecular Biology, University of Texas, 1 University Station A5300, Austin, USA
E-mail: sessler@mail.utexas.edu

Abstract

The synthesis of binuclear organometallic ruthenium complexes of an expanded porphyrin-type macrocycle is reported; pyrrolic hydrogen bonding donors were found to interact with ancillary ligands in the primary coordination sphere and to stabilize coordinated dioxygen in an η2-fashion.

Graphical abstract: Binuclear organometallic ruthenium complexes of a Schiff base expanded porphyrin

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Article information

DOI
https://doi.org/10.1039/B807126H
Article type
Communication
Submitted
01 May 2008
Accepted
11 Jun 2008
First published
01 Jul 2008

Chem. Commun., 2008, 3744-3746

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Binuclear organometallic ruthenium complexes of a Schiff base expanded porphyrin

L. Cuesta, E. Tomat, V. M. Lynch and J. L. Sessler, Chem. Commun., 2008, 3744 DOI: 10.1039/B807126H

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