Issue 39, 2008
From the journal:

Chemical Communications

Total syntheses of (±)-montanin A and (±)-teuscorolide†

I-Chia Chen,a   Yen-Ku Wu,a   Hsing-Jang Liu*a  and  Jiang-Liang Zhu*b  

* Corresponding authors

a Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan ROC
E-mail: hjliu@mx.nthu.edu.tw

b Department of Chemistry, National Dong-Hwa University, Hualien, Taiwan ROC
E-mail: jlzhu@mail.ndhu.edu.tw

Abstract

The first total syntheses of (±)-montanin A and (±)-teuscorolide have been achieved from an advanced precursor previously developed via a Diels–Alder strategy; in the synthetic sequence, the synthesis of montanin A was first accomplished in 8 steps, from which teuscorolide was readily achieved in 2 steps by using a novel furan oxidative cyclization–retro-cyclization process as a key operation.

Graphical abstract: Total syntheses of (±)-montanin A and (±)-teuscorolide

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Article information

DOI
https://doi.org/10.1039/B807218C
Article type
Communication
Submitted
29 Apr 2008
Accepted
11 Jul 2008
First published
02 Sep 2008

Chem. Commun., 2008, 4720-4722

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Total syntheses of (±)-montanin A and (±)-teuscorolide

I. Chen, Y. Wu, H. Liu and J. Zhu, Chem. Commun., 2008, 4720 DOI: 10.1039/B807218C

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