Issue 44, 2008

New 6-oxa-2-silabicyclo[2.2.0]hexanes by photochemical conversion of acyl(allyl)(dimethyl)silanes

Abstract

Under UV irradiation in acetonitrile, acyl(allyl)silanes undergo an intramolecular (2+2) cycloaddition (Paternò-Büchi type reaction) to give unprecedented 1-alkyl-6-oxa-2-silabicyclo[2.2.0] hexanes.

Graphical abstract: New 6-oxa-2-silabicyclo[2.2.0]hexanes by photochemical conversion of acyl(allyl)(dimethyl)silanes

Supplementary files

Article information

Article type
Communication
Submitted
22 Jul 2008
Accepted
26 Aug 2008
First published
30 Sep 2008

Chem. Commun., 2008, 5833-5835

New 6-oxa-2-silabicyclo[2.2.0]hexanes by photochemical conversion of acyl(allyl)(dimethyl)silanes

C. Hammaecher and C. Portella, Chem. Commun., 2008, 5833 DOI: 10.1039/B812550C

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