Issue 46, 2008
From the journal:

Chemical Communications

Long-distance ferromagnetic coupling through spin polarization in a linear heterotrinuclear iron(iii)–copper(ii)–iron(iii) complex derived from 5-ferrocenyl-2-aminotropone†

Yoshihiro Miyake,‡a   Sayaka Watanabe,a   Satoshi Aono,a   Tohru Nishinaga,*a   Akira Miyazaki,b   Toshiaki Enoki,b   Hitoshi Miyasaka,§a   Hiroyuki Otanic  and  Masahiko Iyoda*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, Hachioji, Tokyo, Japan
E-mail: iyoda@tmu.ac.jp
Fax: (+81)42-677-2525
Tel: (+81)42-677-2547

b Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo, Japan
E-mail: enoki.t.aa@m.titech.ac.jp

c Faculty of Education and Human Sciences, Yokohama National University, Hodogaya-ku, Yokohama, Kanagawa, Japan
E-mail: otani@ed.ynu.ac.jp

Abstract

A novel hetrotrinuclear complex composed of two ferrocenium-ion moieties and copper complex of 2-aminotropones showed relatively strong intramolecular ferromagnetic coupling in the solid states owing to spin polarization mechanism.

Graphical abstract: Long-distance ferromagnetic coupling through spin polarization in a linear heterotrinuclear iron(iii)–copper(ii)–iron(iii) complex derived from 5-ferrocenyl-2-aminotropone

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Article information

DOI
https://doi.org/10.1039/B813944J
Article type
Communication
Submitted
12 Aug 2008
Accepted
25 Sep 2008
First published
16 Oct 2008

Chem. Commun., 2008, 6167-6169

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Long-distance ferromagnetic coupling through spin polarization in a linear heterotrinuclear iron(III)–copper(II)–iron(III) complex derived from 5-ferrocenyl-2-aminotropone

Y. Miyake, S. Watanabe, S. Aono, T. Nishinaga, A. Miyazaki, T. Enoki, H. Miyasaka, H. Otani and M. Iyoda, Chem. Commun., 2008, 6167 DOI: 10.1039/B813944J

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