Issue 2, 2008
From the journal:

Chemical Communications

1-Phosphabarrelene complexes of palladium and their use in Suzuki–Miyaura coupling reactions†

Matthias Blug,a   Clément Guibert,a   Xavier-Frederic Le Goff,a   Nicolas Mézailles*a  and  Pascal Le Floch*a  

* Corresponding authors

a Laboratoire “Hétéroéléments et Coordination”, Ecole Polytechnique, CNRS, France
E-mail: pascal.lefloch@polytechnique.edu
Fax: +33 169 44 40
Tel: +33 169 44 01

Abstract

A bulky 1-phosphabarrelene, 2, was obtained from the reaction of a phosphinine with benzyne; two palladium complexes of 2 were successfully employed in the Suzuki–Miyaura coupling of several aryl chlorides with phenylboronic acid at a relatively low catalyst loading, and activated aryl chlorides were coupled at room temperature in the absence of strong bases.

Graphical abstract: 1-Phosphabarrelene complexes of palladium and their use in Suzuki–Miyaura coupling reactions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B814886D
Article type
Communication
Submitted
27 Aug 2008
Accepted
30 Sep 2008
First published
13 Nov 2008

Chem. Commun., 2008

Permissions

Request permissions

1-Phosphabarrelene complexes of palladium and their use in Suzuki–Miyaura coupling reactions

M. Blug, C. Guibert, X. Le Goff, N. Mézailles and P. Le Floch, Chem. Commun., 2008 DOI: 10.1039/B814886D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements