Issue 5, 2009

Mesostructured material based on [Re6Te8(CN)6]4cluster and Mn2+: a rational synthesis of hexagonal nonoxidic mesoscale material

Abstract

A new nonoxidic mesostructured material with highly ordered hexagonal symmetry, [C16H33N(CH3)3]3Mn0.5[Re6Te8(CN)6], has been obtained through supramolecular assembly of [Re6Te8(CN)6]4clusters in the presence of a transition metal cation, Mn2+, with cetyltrimethylammonium bromide as a liquid crystal template under hydrothermal conditions.

Graphical abstract: Mesostructured material based on [Re6Te8(CN)6]4−cluster and Mn2+: a rational synthesis of hexagonal nonoxidic mesoscale material

Supplementary files

Article information

Article type
Communication
Submitted
12 Sep 2008
Accepted
06 Nov 2008
First published
05 Dec 2008

Chem. Commun., 2009, 541-543

Mesostructured material based on [Re6Te8(CN)6]4cluster and Mn2+: a rational synthesis of hexagonal nonoxidic mesoscale material

V. Vien, M. Suh, S. Huh, Y. Kim and S. Kim, Chem. Commun., 2009, 541 DOI: 10.1039/B816000G

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