Issue 11, 2009

Bridgeheadenolates and bridgeheadalkenes in a welwistatin model series

Abstract

Bridgehead metallation is possible in a ketone having the welwistatin skeleton, and this facilitates installation of the isothiocyanate function present in the natural product, and also enables synthesis of remarkable bridgehead alkenes.

Graphical abstract: Bridgehead enolates and bridgeheadalkenes in a welwistatin model series

Supplementary files

Article information

Article type
Communication
Submitted
19 Nov 2008
Accepted
17 Dec 2008
First published
21 Jan 2009

Chem. Commun., 2009, 1398-1400

Bridgehead enolates and bridgeheadalkenes in a welwistatin model series

V. Boissel, N. S. Simpkins, G. Bhalay, A. J. Blake and W. Lewis, Chem. Commun., 2009, 1398 DOI: 10.1039/B820674K

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