Issue 13, 2009
From the journal:

Chemical Communications

A small cationic donor–acceptor iridium complex with a long-lived charge-separated state†

Barbara Geißa  and  Christoph Lambert*a  

* Corresponding authors

a Institut für Organische Chemie, Am Hubland, Würzburg, Germany
E-mail: lambert@chemie.uni-wuerzburg.de

Abstract

A cationic cyclometalated iridium complex with a triarylamine donor attached to the primary ligand sphere showed long-lived (0.04 and 1.7 μs) charge-separated states after photoexcitation which are due to a combined Marcus inverted region effect and spin-selection rules.

Graphical abstract: A small cationic donor–acceptor iridium complex with a long-lived charge-separated state

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Article information

DOI
https://doi.org/10.1039/B820744E
Article type
Communication
Submitted
20 Nov 2008
Accepted
23 Jan 2009
First published
11 Feb 2009

Chem. Commun., 2009, 1670-1672

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A small cationic donor–acceptor iridium complex with a long-lived charge-separated state

B. Geiß and C. Lambert, Chem. Commun., 2009, 1670 DOI: 10.1039/B820744E

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