Issue 18, 2009

Vapor-phase silylation for the construction of monomeric silica puncheons in the interlayer micropores of Al-MWW layered precursor

Abstract

Vapor-phase silylation of Al-MWW layered precursor with SiMe2Cl2 and following calcination produced an interlayer-expanded MWW structure with 12-membered ring micropores without delamination as a result of the formation of silica puncheons between the MWW sheets; strong acidity of zeolitic nature was retained.

Graphical abstract: Vapor-phase silylation for the construction of monomeric silica puncheons in the interlayer micropores of Al-MWW layered precursor

Supplementary files

Article information

Article type
Communication
Submitted
05 Jan 2009
Accepted
25 Feb 2009
First published
20 Mar 2009

Chem. Commun., 2009, 2583-2585

Vapor-phase silylation for the construction of monomeric silica puncheons in the interlayer micropores of Al-MWW layered precursor

S. Inagaki and T. Tatsumi, Chem. Commun., 2009, 2583 DOI: 10.1039/B823524D

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