Issue 20, 2009

Highly enantioselective 1,3-dipolar cycloaddition of azomethine ylides catalyzed by AgOAc/TF-BiphamPhos

Abstract

A novel and highly efficient AgOAc/TF-BiphamPhos catalytic system shows excellent reactivity, diastereo-/enantioselectivity and structural scope in asymmetric 1,3-dipolar cycloaddition of azomethine ylides, especially derived from various α-substituted α-amino acids, with N-substituted maleimides and other electron-deficient alkenes.

Graphical abstract: Highly enantioselective 1,3-dipolar cycloaddition of azomethine ylides catalyzed by AgOAc/TF-BiphamPhos

Supplementary files

Article information

Article type
Communication
Submitted
06 Feb 2009
Accepted
23 Mar 2009
First published
24 Apr 2009

Chem. Commun., 2009, 2905-2907

Highly enantioselective 1,3-dipolar cycloaddition of azomethine ylides catalyzed by AgOAc/TF-BiphamPhos

C. Wang, Z. Xue, G. Liang and Z. Lu, Chem. Commun., 2009, 2905 DOI: 10.1039/B902556A

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