Issue 25, 2009
From the journal:

Chemical Communications

Bis-rhodium hexaphyrins: metalation of [28]hexaphyrin and a smooth Hückel aromatic–antiaromatic interconversion†

Harapriya Rath,a   Naoki Aratani,a   Jong Min Lim,b   Jae Seok Lee,b   Dongho Kim,*b   Hiroshi Shinokubo*ac  and  Atsuhiro Osuka*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan
E-mail: osuka@kuchem.kyoto-u.ac.jp
Fax: +81-75-753-3970
Tel: +81-75-753-4008

b Department of Chemistry, Yonsei University, Seoul 120-749, Korea
E-mail: dongho@yonsei.ac.kr
Fax: +82-2-2123-2434

c Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan
E-mail: hshino@apchem.nagoya-u.ac.jp
Fax: +81-52-789-5113
Tel: +81-52-789-5113

Abstract

Metalation of [28]hexaphyrin(1.1.1.1.1.1) with [RhCl(CO)2]2 resulted in the formation of an antiaromatic bis-Rh(I) complex, which can be oxidized to an aromatic bis-Rh(I) complex with retention of its rectangular structure.

Graphical abstract: Bis-rhodium hexaphyrins: metalation of [28]hexaphyrin and a smooth Hückel aromatic–antiaromatic interconversion

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Article information

DOI
https://doi.org/10.1039/B905859A
Article type
Communication
Submitted
24 Mar 2009
Accepted
24 Apr 2009
First published
12 May 2009

Chem. Commun., 2009, 3762-3764

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Bis-rhodium hexaphyrins: metalation of [28]hexaphyrin and a smooth Hückel aromatic–antiaromatic interconversion

H. Rath, N. Aratani, J. M. Lim, J. S. Lee, D. Kim, H. Shinokubo and A. Osuka, Chem. Commun., 2009, 3762 DOI: 10.1039/B905859A

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