Issue 43, 2009
From the journal:

Chemical Communications

An asymmetric organocatalytic approach towards allylic amines and β-keto amino compounds†

Christian Borch Jacobsen,a   Lennart Lykke,a   David Monge,a   Martin Nielsen,a   Lars Krogager Ransborga  and  Karl Anker Jørgensen*a  

* Corresponding authors

a Center for Catalysis, Department of Chemistry, Aarhus University, DK-8000 Aarhus C, Denmark
E-mail: kaj@chem.au.dk
Fax: +45 8619 6199
Tel: +45 8942 3910

Abstract

The enantioselective organocatalysed addition of β-keto benzothiazolesulfones to N-Boc-protected imines, leading to intermediates easily transformed into optically active allylic amines or β-keto amino compounds, is presented.

Graphical abstract: An asymmetric organocatalytic approach towards allylic amines and β-keto amino compounds

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Article information

DOI
https://doi.org/10.1039/B915439F
Article type
Communication
Submitted
29 Jul 2009
Accepted
22 Aug 2009
First published
10 Sep 2009

Chem. Commun., 2009, 6554-6556

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An asymmetric organocatalytic approach towards allylic amines and β-keto amino compounds

C. B. Jacobsen, L. Lykke, D. Monge, M. Nielsen, L. K. Ransborg and K. A. Jørgensen, Chem. Commun., 2009, 6554 DOI: 10.1039/B915439F

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