Issue 5, 2010

Synthesis of HxLi1−xLaTiO4 from quantitative solid-state reactions at room temperature

Abstract

The layered perovskite HLaTiO4 reacts stoichiometrically with LiOH·H2O at room temperature to give targeted compositions in the series HxLi1−xLaTiO4. Remarkably, the Li+ and H+ ions are quantitatively exchanged in the solid state and this allows stoichiometric control of ion exchange for the first time in this important series of compounds.

Graphical abstract: Synthesis of HxLi1−xLaTiO4 from quantitative solid-state reactions at room temperature

Supplementary files

Article information

Article type
Communication
Submitted
07 Oct 2009
Accepted
18 Nov 2009
First published
30 Nov 2009

Chem. Commun., 2010,46, 698-700

Synthesis of HxLi1−xLaTiO4 from quantitative solid-state reactions at room temperature

T. W. S. Yip, E. J. Cussen and D. A. MacLaren, Chem. Commun., 2010, 46, 698 DOI: 10.1039/B920837B

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