Issue 5, 2010

Desymmetrization of 4-hydroxy-2,5-cyclohexadienones by radical cyclization: synthesis of optically pure γ-lactones

Abstract

Optically pure γ-lactones fused onto a cyclohexenone are available by a radical-based method for desymmetrizing 4-hydroxy-2,5-cyclohexadienones.

Graphical abstract: Desymmetrization of 4-hydroxy-2,5-cyclohexadienones by radical cyclization: synthesis of optically pure γ-lactones

Supplementary files

Article information

Article type
Communication
Submitted
08 Oct 2009
Accepted
27 Nov 2009
First published
16 Dec 2009

Chem. Commun., 2010,46, 701-703

Desymmetrization of 4-hydroxy-2,5-cyclohexadienones by radical cyclization: synthesis of optically pure γ-lactones

R. Sunasee and D. L. J. Clive, Chem. Commun., 2010, 46, 701 DOI: 10.1039/B920884D

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