Issue 32, 2010
From the journal:

Chemical Communications

Stereocontrolled synthesis of quaternary cyclopropyl esters†

Christopher D. Bray*a  and  Fabrizio Miniconea  

* Corresponding authors

a Queen Mary University of London, School of Biological and Chemical Sciences, Mile End Road, London, UK
E-mail: c.bray@qmul.ac.uk
Fax: +44 (0)20 7882 7427
Tel: +44 (0)20 7882 3271

Abstract

Treatment of a variety of enantiopure terminal epoxides with the anion of a range of 2-substituted triethylphosphonoacetates leads to an array of quaternary cyclopropyl esters with high yield and diastereocontrol.

Graphical abstract: Stereocontrolled synthesis of quaternary cyclopropyl esters

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Article information

DOI
https://doi.org/10.1039/C0CC01333A
Article type
Communication
Submitted
10 May 2010
Accepted
22 Jun 2010
First published
13 Jul 2010

Chem. Commun., 2010,46, 5867-5869

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Stereocontrolled synthesis of quaternary cyclopropyl esters

C. D. Bray and F. Minicone, Chem. Commun., 2010, 46, 5867 DOI: 10.1039/C0CC01333A

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