Issue 34, 2010
From the journal:

Chemical Communications

Total synthesis of (±)-Vertine with Z-selective RCM as a key step†

Laetitia Chausset-Boissarie,a   Roman Àrvai,a   Graham R. Cumming,a   Céline Besnarda  and  E. Peter Kündig*a  

* Corresponding authors

a Department of Organic Chemistry, University of Geneva, 30, quai Ernest Ansermet, CH-1211 Geneva, Switzerland
E-mail: peter.kundig@unige.ch
Fax: +41 223793215
Tel: +41 223796093

Abstract

A concise total synthesis of the strained pentacyclic alkaloid (±)-Vertine has been achieved in eleven steps with the key steps being pelletierine condensation, Suzuki–Miyaura coupling, and ring-closing metathesis.

Graphical abstract: Total synthesis of (±)-Vertine with Z-selective RCM as a key step

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Article information

DOI
https://doi.org/10.1039/C0CC01885F
Article type
Communication
Submitted
14 Jun 2010
Accepted
09 Jul 2010
First published
11 Aug 2010

Chem. Commun., 2010,46, 6264-6266

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Total synthesis of (±)-Vertine with Z-selective RCM as a key step

L. Chausset-Boissarie, R. Àrvai, G. R. Cumming, C. Besnard and E. P. Kündig, Chem. Commun., 2010, 46, 6264 DOI: 10.1039/C0CC01885F

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