Issue 1, 2011
From the journal:

Chemical Communications

Nickel-catalysed cross-coupling reaction of aryl(trialkyl)silanes with aryl chlorides and tosylates†

Shi Tang,a   Masahide Takeda,a   Yoshiaki Nakao*a  and  Tamejiro Hiyama‡a  

* Corresponding authors

a Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan
E-mail: yoshiakinakao@npc05.mbox.media.kyoto-u.ac.jp
Fax: +81 75 383 2445
Tel: +81 75 383 2443

Abstract

Using highly stable, readily accessible, and recyclable 2-(2-hydroxyprop-2-yl)cyclohexyl-substituted arylsilanes activated by a mild carbonate base, nickel-catalysed silicon-based aryl–aryl cross-coupling reaction proceeds for the first time with inexpensive aryl chlorides and tosylates in a highly chemoselective manner.

Graphical abstract: Nickel-catalysed cross-coupling reaction of aryl(trialkyl)silanes with aryl chlorides and tosylates

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Article information

DOI
https://doi.org/10.1039/C0CC02173C
Article type
Communication
Submitted
29 Jun 2010
Accepted
26 Jul 2010
First published
23 Aug 2010

Chem. Commun., 2011,47, 307-309

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Nickel-catalysed cross-coupling reaction of aryl(trialkyl)silanes with aryl chlorides and tosylates

S. Tang, M. Takeda, Y. Nakao and T. Hiyama, Chem. Commun., 2011, 47, 307 DOI: 10.1039/C0CC02173C

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