Issue 6, 2011

Bis-boranes in the frustrated Lewis pair activation of carbon dioxide

Abstract

Using a frustrated Lewis pair approach, the 1,1-bis-(C6F5)2BOB(C6F5)2 is shown to bind CO2 in a monodentate fashion, while the bis-boranes (X2B)2C[double bond, length as m-dash]CMe2 (X = Cl, C6F5) give bidentate chelation of CO2 affording unique heterocycles.

Graphical abstract: Bis-boranes in the frustrated Lewis pair activation of carbon dioxide

Supplementary files

Additions and corrections

Article information

Article type
Communication
Submitted
04 Nov 2010
Accepted
02 Dec 2010
First published
04 Jan 2011

Chem. Commun., 2011,47, 1833-1835

Bis-boranes in the frustrated Lewis pair activation of carbon dioxide

X. Zhao and D. W. Stephan, Chem. Commun., 2011, 47, 1833 DOI: 10.1039/C0CC04791K

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