Issue 13, 2011
From the journal:

Chemical Communications

A unique 2D → 3D polycatenation cobalt(ii)-based molecule magnet showing coexistence of paramagnetism and canted antiferromagnetism†

Bo Xu,a   Xi Lin,a   Zhangzhen He,a   Zujin Lina  and  Rong Cao*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou 350002, PR China
E-mail: rcao@fjirsm.ac.cn
Fax: +8659183796710
Tel: +8659183796710

Abstract

A novel entangled architecture [Co1.5(bpmp)(Hcda)(cda)(H2O)] (1) based on 44-sql subunits, showing an interesting 2D → 3D inclined polycatenation structure feature, is reported. Magnetic investigation shows that compound 1 exhibits coexistence of paramagnetism and canted antiferromagnetism with Tc of 48 K.

Graphical abstract: A unique 2D → 3D polycatenation cobalt(ii)-based molecule magnet showing coexistence of paramagnetism and canted antiferromagnetism

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Article information

DOI
https://doi.org/10.1039/C0CC05567K
Article type
Communication
Submitted
14 Dec 2010
Accepted
18 Feb 2011
First published
28 Feb 2011

Chem. Commun., 2011,47, 3766-3768

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A unique 2D → 3D polycatenation cobalt(II)-based molecule magnet showing coexistence of paramagnetism and canted antiferromagnetism

B. Xu, X. Lin, Z. He, Z. Lin and R. Cao, Chem. Commun., 2011, 47, 3766 DOI: 10.1039/C0CC05567K

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