Issue 13, 2011
From the journal:

Chemical Communications

Heteroleptic [1]zirconametalloarenophanes: potential precursors to metal-enriched metallopolymers†

Holger Braunschweig,*a   Maria Friedrich,a   Thomas Kupfera  and  Krzysztof Radackia  

* Corresponding authors

a Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany
E-mail: h.braunschweig@mail.uni-wuerzburg.de
Fax: +49 931 31 84623
Tel: +49 931 31 85260

Abstract

[1]Zirconametalloarenophanes [Cr(η5-C5H4)ZrCp′2(η7-C7H6)] and [Mn(η5-C5H4)ZrCp′2(η6-C6H5)] (Cp′ = C5H4tBu) have been isolated for the first time. These species represent potential precursors en route to metal-enriched metallopolymers by ROP. The electronic structure was assessed by means of UV-visible spectroscopy and TD-DFT calculations.

Graphical abstract: Heteroleptic [1]zirconametalloarenophanes: potential precursors to metal-enriched metallopolymers

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Article information

DOI
https://doi.org/10.1039/C1CC10207A
Article type
Communication
Submitted
12 Jan 2011
Accepted
07 Feb 2011
First published
18 Feb 2011

Chem. Commun., 2011,47, 3998-4000

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Heteroleptic [1]zirconametalloarenophanes: potential precursors to metal-enriched metallopolymers

H. Braunschweig, M. Friedrich, T. Kupfer and K. Radacki, Chem. Commun., 2011, 47, 3998 DOI: 10.1039/C1CC10207A

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