Issue 13, 2011
From the journal:

Chemical Communications

Highly efficient desymmetrisation of a tricarbonylchromium 1,4-dibromonaphthalene complex by asymmetric Suzuki–Miyaura coupling‡

Xavier Urbaneja,a   Audrey Mercier,a   Céline Besnarda  and  E. Peter Kündig*a  

* Corresponding authors

a Department of Organic Chemistry, University of Geneva, Quai Ernest Ansermet 30, 1211 Geneva 4, Switzerland
E-mail: Peter.Kundig@unige.ch

Abstract

Access to planar chiral complexes has been sought by catalytic desymmetrisation of a prochiral complex via asymmetric Suzuki–Miyaura cross-coupling. High selectivities of up to 98% ee were achieved using a bulky chiral palladium catalyst.

Graphical abstract: Highly efficient desymmetrisation of a tricarbonylchromium 1,4-dibromonaphthalene complex by asymmetric Suzuki–Miyaura coupling

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Article information

DOI
https://doi.org/10.1039/C1CC10347D
Article type
Communication
Submitted
18 Jan 2011
Accepted
10 Feb 2011
First published
28 Feb 2011

Chem. Commun., 2011,47, 3739-3741

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Highly efficient desymmetrisation of a tricarbonylchromium 1,4-dibromonaphthalene complex by asymmetric Suzuki–Miyaura coupling

X. Urbaneja, A. Mercier, C. Besnard and E. P. Kündig, Chem. Commun., 2011, 47, 3739 DOI: 10.1039/C1CC10347D

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