Issue 17, 2011
From the journal:

Chemical Communications

Induction in urothermal synthesis of chiral porous materials from achiral precursors†

Yao Kang,a   Shumei Chen,ab   Fei Wang,a   Jian Zhang*a  and  Xianhui Bu*c  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: zhj@fjirsm.ac.cn

b College of Chemistry & Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350, P. R. China

c Department of Chemistry and Biochemistry, California State University, Long Beach, 1250 Bellflower Boulevard, Long Beach, USA
E-mail: xbu@csulb.edu

Abstract

Special asymmetric crystallization of porous framework materials from achiral precursors under urothermal conditions is successfully achieved by using an enantiopure liquid as a co-solvent and chirality induction agent, which provides a new strategy for the synthesis of homochiral porous materials containing only achiral building blocks.

Graphical abstract: Induction in urothermal synthesis of chiral porous materials from achiral precursors

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Article information

DOI
https://doi.org/10.1039/C1CC10486A
Article type
Communication
Submitted
25 Jan 2011
Accepted
11 Mar 2011
First published
25 Mar 2011

Chem. Commun., 2011,47, 4950-4952

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Induction in urothermal synthesis of chiral porous materials from achiral precursors

Y. Kang, S. Chen, F. Wang, J. Zhang and X. Bu, Chem. Commun., 2011, 47, 4950 DOI: 10.1039/C1CC10486A

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