Issue 29, 2011
From the journal:

Chemical Communications

Top-down fabrication of crystalline metal–organic framework nanosheets†

Pei-Zhou Li,ab   Yasushi Maedaa  and  Qiang Xu*ab  

* Corresponding authors

a National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka, Japan
E-mail: q.xu@aist.go.jp
Fax: +81-72-751-9629
Tel: +81-72-751-9562

b Graduate School of Engineering, Kobe University, Nada Ku, Kobe, Hyogo, Japan

Abstract

Crystalline metal–organic framework (MOF) nanosheets have been fabricated via top-down delamination from bulk crystals of a layered MOF, {Zn(TPA)(H2O)·DMF}n (MOF-2), and characterized by Tyndall scattering, scanning electron microscopy and atomic force microscopy measurements. The delaminated MOF-2 nanosheets exhibit remarkable amine intercalation property and reversible amine exchangeability.

Graphical abstract: Top-down fabrication of crystalline metal–organic framework nanosheets

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Article information

DOI
https://doi.org/10.1039/C1CC12510A
Article type
Communication
Submitted
29 Apr 2011
Accepted
09 Jun 2011
First published
27 Jun 2011

Chem. Commun., 2011,47, 8436-8438

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Top-down fabrication of crystalline metal–organic framework nanosheets

P. Li, Y. Maeda and Q. Xu, Chem. Commun., 2011, 47, 8436 DOI: 10.1039/C1CC12510A

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