Issue 1, 2012
From the journal:

Chemical Communications

Fe-catalysed oxidative C–H functionalization/C–S bond formation†

Haibo Wang,a   Lu Wang,a   Jinsai Shang,a   Xing Li,a   Haoyuan Wang,a   Jie Guia  and  Aiwen Lei*ab  

* Corresponding authors

a College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, P. R. China
E-mail: aiwenlei@whu.edu.cn
Fax: +86-27-68754672
Tel: +86-27-68754672

b State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, 730000, Lanzhou, P. R. China

Abstract

Iron was used as the catalyst for the direct C–H functionalization/C–S bond formation under mild conditions. Various substrates could afford benzothiazoles in moderate to excellent yields. Preliminary mechanistic studies revealed that pyridine played a crucial role for the high yields and selectivities.

Graphical abstract: Fe-catalysed oxidative C–H functionalization/C–S bond formation

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Article information

DOI
https://doi.org/10.1039/C1CC16184A
Article type
Communication
Submitted
05 Oct 2011
Accepted
08 Nov 2011
First published
08 Nov 2011

Chem. Commun., 2012,48, 76-78

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Fe-catalysed oxidative C–H functionalization/C–S bond formation

H. Wang, L. Wang, J. Shang, X. Li, H. Wang, J. Gui and A. Lei, Chem. Commun., 2012, 48, 76 DOI: 10.1039/C1CC16184A

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