Na3PO4-catalyzed aminochlorination reaction of β-nitrostyrenes in water

Haibo Mei; Yiwen Xiong; Yu Qian; Jianlin Han; Guigen Li; Yi Pan

doi:10.1039/C1RA00679G

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Na₃PO₄-catalyzed aminochlorination reaction of β-nitrostyrenes in water†

Haibo Mei,^a Yiwen Xiong,^a Yu Qian,^a Jianlin Han,*^a Guigen Li^b and Yi Pan*^a

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* Corresponding authors

^a School of Chemistry and Chemical Engineering, Nanjing University, State of Key Laboratory of Coordination, Nanjing University, Nanjing, China
E-mail: hanjl@nju.edu.cn, yipan@nju.edu.cn
Fax: 86-25-83593153
Tel: 86-25-83593153

^b Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, Texas, USA

Abstract

A facile and green aminochlorination of β-nitrostyrenes has been developed by using t-butyl N,N-dichlorocarbamate (BocNCl₂) as a nitrogen/chlorine source in water at room temperature, which tolerated a wide range of substrates and resulted in the highest efficiency so far.

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Article information

DOI: https://doi.org/10.1039/C1RA00679G
Article type: Paper
Submitted: 05 Sep 2011
Accepted: 06 Sep 2011
First published: 27 Oct 2011

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RSC Adv., 2012,2, 151-155

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Na₃PO₄-catalyzed aminochlorination reaction of β-nitrostyrenes in water

H. Mei, Y. Xiong, Y. Qian, J. Han, G. Li and Y. Pan, RSC Adv., 2012, 2, 151 DOI: 10.1039/C1RA00679G

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