Issue 50, 2012
From the journal:

Chemical Communications

Recoverable organorhodium-functionalized polyhedral oligomeric silsesquioxane: a bifunctional heterogeneous catalyst for asymmetric transfer hydrogenation of aromatic ketones in aqueous medium†

Shuang Tang,a   Ronghua Jin,a   Huaisheng Zhang,a   Hui Yao,a   Jinglan Zhuang,a   Guohua Liu*a  and  Hexing Li*a  

* Corresponding authors

a The Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Normal University, Shanghai, China
E-mail: ghliu@shnu.edu.cn, HeXing-Li@shnu.edu.cn
Tel: +8621 64321819

Abstract

A bifuctional heterogeneous chiral rhodium catalyst exhibited excellent catalytic activity and enantioselectivity in asymmetric transfer hydrogenation of aromatic ketones and their analogues in aqueous medium, which could be recovered easily and used repetitively without affecting obviously its enantioselectivity.

Graphical abstract: Recoverable organorhodium-functionalized polyhedral oligomeric silsesquioxane: a bifunctional heterogeneous catalyst for asymmetric transfer hydrogenation of aromatic ketones in aqueous medium

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Article information

DOI
https://doi.org/10.1039/C2CC31927F
Article type
Communication
Submitted
16 Mar 2012
Accepted
03 May 2012
First published
03 May 2012

Chem. Commun., 2012,48, 6286-6288

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Recoverable organorhodium-functionalized polyhedral oligomeric silsesquioxane: a bifunctional heterogeneous catalyst for asymmetric transfer hydrogenation of aromatic ketones in aqueous medium

S. Tang, R. Jin, H. Zhang, H. Yao, J. Zhuang, G. Liu and H. Li, Chem. Commun., 2012, 48, 6286 DOI: 10.1039/C2CC31927F

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