Issue 63, 2012

Core–shell structured mesoporous silica: a new immobilized strategy for rhodium catalyzed asymmetric transfer hydrogenation

Abstract

A core–shell structured heterogeneous rhodium catalyst exhibited excellent catalytic activity and enantioselectivity in asymmetric transfer hydrogenation of aromatic ketones in aqueous medium, which could be recovered easily and used repetitively twelve times without affecting obviously its enantioselectivity.

Graphical abstract: Core–shell structured mesoporous silica: a new immobilized strategy for rhodium catalyzed asymmetric transfer hydrogenation

Supplementary files

Article information

Article type
Communication
Submitted
15 May 2012
Accepted
19 Jun 2012
First published
19 Jun 2012

Chem. Commun., 2012,48, 7874-7876

Core–shell structured mesoporous silica: a new immobilized strategy for rhodium catalyzed asymmetric transfer hydrogenation

H. Zhang, R. Jin, H. Yao, S. Tang, J. Zhuang, G. Liu and H. Li, Chem. Commun., 2012, 48, 7874 DOI: 10.1039/C2CC33512C

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