Issue 12, 2013
From the journal:

Chemical Communications

A cyanide and hydroxo-bridged nanocage: a new generation of coordination clusters†

Abhishake Mondal,a   Sonja Durdevic,a   Lise-Marie Chamoreau,a   Yves Journaux,a   Miguel Julve,b   Laurent Lisnard*a  and  Rodrigue Lescouëzec*a  

* Corresponding authors

a Institut Parisien de Chimie Moléculaire, UMR 7201, UPMC, Univ Paris 06, Paris, 75005 Paris, France
E-mail: rodrigue.lescouezec@upmc.fr
Fax: 0033 (0)1 44 27 38 41
Tel: 0033 (0)1 44 27 55 62

b Instituto de Ciencia Molecular (ICMol), Facultat de Química, Universitat de València, C/Catedrático José Beltrán 2, 46980 Paterna, València, Spain

Abstract

Combining serendipitously-formed hydroxo-clusters, [CoII3(OH)(piv)4(L)]+ (where L = MeCN or Hpiv), with assembling cyanide building block, [FeIII(Tp)(CN)3]−, has led to an unprecedented architecture where polymetallic cobalt clusters and blocked tris-cyanide iron complexes define the apexes of a unique magnetic cubic nanocage.

Graphical abstract: A cyanide and hydroxo-bridged nanocage: a new generation of coordination clusters

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Article information

DOI
https://doi.org/10.1039/C2CC38404C
Article type
Communication
Submitted
22 Nov 2012
Accepted
18 Dec 2012
First published
19 Dec 2012

Chem. Commun., 2013,49, 1181-1183

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A cyanide and hydroxo-bridged nanocage: a new generation of coordination clusters

A. Mondal, S. Durdevic, L. Chamoreau, Y. Journaux, M. Julve, L. Lisnard and R. Lescouëzec, Chem. Commun., 2013, 49, 1181 DOI: 10.1039/C2CC38404C

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