Issue 27, 2012

Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour

Abstract

The synthesis and characterization of a new class of cationic (NHC)gold(I) (NHC = N-Heterocyclic carbene) complex containing the phosphate counterions TRISPHAT and TRISPHAT-N have been achieved. The selection of the appropriate hexacoordinated phosphate architecture permits the isolation of complexes bearing an inner or outer sphere anionic counterion.

Graphical abstract: Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour

Supplementary files

Article information

Article type
Communication
Submitted
23 Feb 2012
Accepted
16 May 2012
First published
31 May 2012

Dalton Trans., 2012,41, 8235-8237

Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour

S. Gaillard, D. Rix, A. M. Z. Slawin, J. Lacour and S. P. Nolan, Dalton Trans., 2012, 41, 8235 DOI: 10.1039/C2DT30440F

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