Issue 1, 2013

Ruthenium(ii)-catalyzed selective monoarylation in water and sequential functionalisations of C–H bonds

Abstract

The ruthenium(II)-phosphine catalyst RuCl2(PPh3)(p-cymene) operating water selectively leads to ortho monoarylation, with arylchlorides and heteroarylhalides, of functional arenes. Further catalytic heteroarylation with Ru(OAc)2(p-cymene) in water produces mixed bifunctional derivatives.

Graphical abstract: Ruthenium(ii)-catalyzed selective monoarylation in water and sequential functionalisations of C–H bonds

Supplementary files

Article information

Article type
Communication
Submitted
02 Aug 2012
Accepted
28 Sep 2012
First published
01 Oct 2012

Green Chem., 2013,15, 67-71

Ruthenium(II)-catalyzed selective monoarylation in water and sequential functionalisations of C–H bonds

P. B. Arockiam, C. Fischmeister, C. Bruneau and P. H. Dixneuf, Green Chem., 2013, 15, 67 DOI: 10.1039/C2GC36222H

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