Issue 27, 2013
From the journal:

Chemical Communications

Dirhodium(ii)-catalyzed formal [3+2+1]-annulation of azomethineimines with two molecules of a diazo ketone†

Xinfang Xu,a   Xichen Xu,a   Peter Y. Zavalija  and  Michael P. Doyle*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland, USA
E-mail: mdoyle3@umd.edu

Abstract

A highly diastereoselective formal [3+2+1]-cycloaddition reaction that produces multi-functionalized bicyclic pyrazolidinone derivatives is achieved in moderate to high yield by Rh2(4S-MPPIM)4-catalyzed reaction of azomethine imines with two molecules of a diazo ketone.

Graphical abstract: Dirhodium(ii)-catalyzed formal [3+2+1]-annulation of azomethine imines with two molecules of a diazo ketone

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC41119B
Article type
Communication
Submitted
09 Feb 2013
Accepted
19 Feb 2013
First published
22 Feb 2013

Chem. Commun., 2013,49, 2762-2764

Permissions

Request permissions

Dirhodium(II)-catalyzed formal [3+2+1]-annulation of azomethine imines with two molecules of a diazo ketone

X. Xu, X. Xu, P. Y. Zavalij and M. P. Doyle, Chem. Commun., 2013, 49, 2762 DOI: 10.1039/C3CC41119B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements