A ferromagnetically coupled diphenoxo-bridged Gd3+–Mn2+ dinuclear complex with a large magneto-caloric effect

Enrique Colacio; José Ruiz; Giulia Lorusso; Euan K. Brechin; Marco Evangelisti

doi:10.1039/C3CC41483C

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A ferromagnetically coupled diphenoxo-bridged Gd³⁺–Mn²⁺ dinuclear complex with a large magneto-caloric effect†‡§

Enrique Colacio,*^a José Ruiz,^a Giulia Lorusso,^b Euan K. Brechin*^c and Marco Evangelisti*^b

Author affiliations

* Corresponding authors

^a Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, Av. Fuentenueva S/N, 18071 Granada, Spain
E-mail: ecolacio@ugr.es

^b Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, Departamento de Física de la Materia Condensada, 50009 Zaragoza, Spain
E-mail: evange@unizar.es
Web: http://molchip.unizar.es/

^c EaStCHEM School of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh, UK
E-mail: ebrechin@staffmail.ed.ac.uk

Abstract

A novel diphenoxo-bridged Gd³⁺–Mn²⁺ dimer is proposed as a good candidate for cryogenic magnetic refrigeration. The large MCE is enhanced by the ferromagnetic interaction between the two metal ions.

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Article information

DOI: https://doi.org/10.1039/C3CC41483C
Article type: Communication
Submitted: 26 Feb 2013
Accepted: 22 Mar 2013
First published: 22 Mar 2013
This article is Open Access

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Chem. Commun., 2013,49, 3845-3847

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A ferromagnetically coupled diphenoxo-bridged Gd³⁺–Mn²⁺ dinuclear complex with a large magneto-caloric effect

E. Colacio, J. Ruiz, G. Lorusso, E. K. Brechin and M. Evangelisti, Chem. Commun., 2013, 49, 3845 DOI: 10.1039/C3CC41483C

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