Issue 88, 2013
From the journal:

Chemical Communications

A polycyclic borazine radical cation: [1,2-B2{1,2-(MeN)2C6H4}2]˙+†

Xiaochen Xie,a   Christopher J. Adams,a   Muhsen A. M. Al-Ibadi,‡b   John E. McGrady,b   Nicholas C. Norman*a  and  Christopher A. Russell*a  

* Corresponding authors

a University of Bristol, School of Chemistry, Bristol, UK
E-mail: Chris.Russell@bristol.ac.uk, n.c.norman@bristol.ac.uk

b Department of Chemistry, Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, UK

Abstract

The radical cation [1,2-B2{1,2-(MeN)2C6H4}2]˙+ has been synthesised and its structure and bonding have been probed using a combination of X-ray crystallography, EPR spectroscopy and DFT calculations which show that it represents a new type of radical centred primarily on two N-heterocyclic units joined by a B2 linker but with only a minor contribution from boron-based orbitals.

Graphical abstract: A polycyclic borazine radical cation: [1,2-B2{1,2-(MeN)2C6H4}2]˙+

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Article information

DOI
https://doi.org/10.1039/C3CC44990D
Article type
Communication
Submitted
03 Jul 2013
Accepted
23 Sep 2013
First published
24 Sep 2013

Chem. Commun., 2013,49, 10364-10366

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A polycyclic borazine radical cation: [1,2-B2{1,2-(MeN)2C6H4}2]˙+

X. Xie, C. J. Adams, M. A. M. Al-Ibadi, J. E. McGrady, N. C. Norman and C. A. Russell, Chem. Commun., 2013, 49, 10364 DOI: 10.1039/C3CC44990D

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